Silk Road forums

Market => Product requests => Topic started by: Kheper on May 23, 2013, 02:40 pm

Title: Chloroform?
Post by: Kheper on May 23, 2013, 02:40 pm
Anybody on here know where i can get a litre of chloroform?

cheers
Title: Re: Chloroform?
Post by: Tyrion Lannister on May 23, 2013, 02:52 pm
how much are you willing to pay for it ?
Title: Re: Chloroform?
Post by: chemdog on May 24, 2013, 08:16 pm
Next question: where would it be shipping to?
Title: Re: Chloroform?
Post by: Jack N Hoff on May 24, 2013, 08:57 pm
A legitimate vendor on atlantis or BMR carried chloroform.  I believe it's atlantis but I'm not positive.
Title: Re: Chloroform?
Post by: tree on May 26, 2013, 07:19 pm
You can buy chloroform on eBay or on science sites, it's not illegal.
Title: Re: Chloroform?
Post by: jackofspades on May 27, 2013, 12:47 pm
Ask Casey Anthony
Title: Re: Chloroform?
Post by: ChemCat on May 27, 2013, 10:13 pm
Chloroform

http://silkroadvb5piz3r.onion/silkroad/item/6f9c359a31


Title: Re: Chloroform?
Post by: Kheper on May 29, 2013, 01:15 am
cheers mate
Title: Re: Chloroform?
Post by: DayDreamer on May 29, 2013, 01:57 am
Buy some bleach.
Buy some acetone
Mix the 2 together.

there's your chloroform.

There is a youtube video with instructions.

Title: Re: Chloroform?
Post by: wraithe on May 29, 2013, 08:16 pm
Buy some bleach.
Buy some acetone
Mix the 2 together.

there's your chloroform.

There is a youtube video with instructions.
source erowid

With Calcium Hypochlorite and Acetone

When chlorine is passed into boiling alcohol, both chlorination of the methyl group and oxidation of the primary alcohol group to an aldehyde occur, giving trichloro-acetaldehyde or chloral: When chloral is treated with caustic alkali, fission of the C-C linkage occurs, giving chloroform and a formate. Acetaldehyde and also many ketones, such as acetone, containing the CH3CO- group behave similarly when treated with calcium or sodium hypochlorite, chlorination of the CH3CO- group being immediately followed by fission of the molecule by the alkali present in the hypochlorite solution. The acetone method clearly gives a much cheaper product than the alcohol method.

Required: Calcium Hypochlorite 100g (bleaching powder), acetone 44ml

Place 100g of calcium hypochlorite in a mortar and add 250 ml of water in small quantities at a time: between each addition grind the mixture of bleaching powder and water well together and decant the cream-like suspension through a funnel into a 1-litre flat-bottomed flask. Finally, when all the water has thus been used, only a gritty residue remains in the mortar. Fit the flask with an efficient reflux water-condenser, pour 44ml (35g) of acetone in small quantities, at a time, down the condenser and mix by thorough shaking after each addition. The reaction usually starts spontaneously after a few minutes, and a bath of cold water should be available into which the flask may be dipped if necessary to moderate the reaction. Should the reaction show no signs of starting within 5 minutes of the addition of the acetone, warm the flask cautiously on a boiling water-bath until the reaction starts, and then remove it immediately. When the vigorous boiling has subsided, heat the flask on a boiling water-bath for a further 5-10 minutes (not more) to complete the reaction. Cool the flask in cold water (to prevent loss of chloroform vapour whilst the apparatus is being rearranged) and then fit the flask with a fairly wide delivery-tube and reverse the water-condenser for distillation. Heat the flask on a water-bath until distillation of the chloroform is complete.

The chloroform thus obtained is usually acidic. Therefore shake it thoroughly with dilute sodium hydroxide solution in a separating-funnel. (If the chloroform tends to float on the alkaline solution, it still contains appreciable quantities of acetone: in this case the soda should be run out of the funnel and the chloroform shaken with water to extract the acetone. The extraction with the soda can then be performed after the water has been removed.) Carefully run off the heavy lower layer of chloroform into a small conical flask, dry it over calcium chloride for 15-20 minutes, and then filter it directly into a 75 ml. distilling-flask fitted with a clean dry water-condenser. Distill the chloroform, collecting the fraction of bp. 60-63øC. Yield, 30g. (20ml).

Chloroform is a colourless liquid, of bp 61ø and d 1.50. It has a characteristic sweetish smell, and is frequently used as a solvent in organic chemistry.

Reference: Mann & Saunders, Practical Organic Chemistry, 3rd Ed
I hope this is a fucking joke.  That makes mustard gas...  I've been locked in a confined space with no ventilation and bleach an acetone being mixed all around me. :(
Title: Re: Chloroform?
Post by: wraithe on May 29, 2013, 08:19 pm
Buy some bleach.
Buy some acetone
Mix the 2 together.

there's your chloroform.

There is a youtube video with instructions.

I hope this is a fucking joke.  That makes mustard gas...  I've been locked in a confined space with no ventilation and bleach an acetone being mixed all around me. :(

bleach + ammonia = chlorine gas often mistakenly called mustard gas.
Title: Re: Chloroform?
Post by: Jack N Hoff on May 29, 2013, 09:42 pm
Buy some bleach.
Buy some acetone
Mix the 2 together.

there's your chloroform.

There is a youtube video with instructions.

I hope this is a fucking joke.  That makes chlorine gas...  I've been locked in a confined space with no ventilation and bleach an acetone being mixed all around me. :(

bleach + ammonia = chlorine gas often mistakenly called mustard gas.

I stand corrected.  Chlorine gas is very deadly though.  Swimming pool service workers have died from it.  I knew of one case where he put the chlorine tank in the passenger seat instead of the bed of the truck after a job because he was rushing.  It was leaking and he died.
Title: Re: Chloroform?
Post by: wraithe on May 29, 2013, 11:30 pm
Buy some bleach.
Buy some acetone
Mix the 2 together.

there's your chloroform.

There is a youtube video with instructions.

I hope this is a fucking joke.  That makes chlorine gas...  I've been locked in a confined space with no ventilation and bleach an acetone being mixed all around me. :(

bleach + ammonia = chlorine gas often mistakenly called mustard gas.

I stand corrected.  Chlorine gas is very deadly though.  Swimming pool service workers have died from it.  I knew of one case where he put the chlorine tank in the passenger seat instead of the bed of the truck after a job because he was rushing.  It was leaking and he died.

I wasnt trying to take away from the fact you almost killed yourself lol your still a crazy fuck.  its not everyday I am smarter then Jack so I figured id pounce on it, I didnt see it happening again
Title: Re: Chloroform?
Post by: ChemCat on May 30, 2013, 01:15 am
Jack, please tell me that you didnt mix amonia and bleach trying to make mustard.....i'll send ya some gey pupon :P


just kiddin ya  (Hugs)

:)

Peace,

ChemCat O0
Title: Re: Chloroform?
Post by: Jack N Hoff on May 30, 2013, 01:31 am
Jack, please tell me that you didnt mix amonia and bleach trying to make mustard.....i'll send ya some gey pupon :P


just kiddin ya  (Hugs)

:)

Peace,

ChemCat O0

Well you know me, as I said before, I only deal in Grey Poupon and fresh napkins so I'll gladly take you up on that generous offer. O0

I'm starting a cheese orchard where Italian and French cheese grows on trees in balls to form Cheese-Apples that turn into iPhones and they can do that because they have the name Apple in them. Want to buy some apps? How about some pants? Maybe some socks? No? Well go fuck yourself then.

I'm interested in rooted cuttings of the cheese ball apple orchards that turn into iPhones.  PM me if you have some available.

37 CAMELS AND SIX-PENCE! EXCELLENT DEAL! I THROW IN 3 SACHETS OF MUSTARD AND 1 USED NAPKIN! GOOD DEAL!

I only deal in Gray Poupon and fresh unused napkins.  Not just any run of the mill mustard, sorry.
Title: Re: Chloroform?
Post by: ChemCat on May 30, 2013, 01:35 am
^^^^ This  is another reason i like Jack  :)

Title: Re: Chloroform?
Post by: ChemCat on May 30, 2013, 01:39 am
Jack i wish m,ymmemory was half as good as yours  (Hugs)

man oh man if my memory loss isnt early alzheimers i dont know what is   :-\